Water and Oil Do Mix – On Saturn‘s Moon Titan,Scientists Find
PASADENA,CA – In a discovery challenging fundamental chemistry principles,scientists have found that โsubstances typically considered incompatible โข- โlike oil and water โข- can โcombine too โฃform stable structuresโ onโค Saturn’s moon Titan. A team from NASA and Chalmers University of Technologyโ demonstrated that hydrogen cyanide, a polar molecule, can form co-crystals with nonpolar hydrocarbons like methaneโ and ethane, conditions mirroring โTitan’s surface.
The finding, โpublished in โคthe journal PNAS, upends โthe conventional “like dissolves like” rule of chemistry, where polar molecules attract otherโ polar molecules and โฃrepel nonpolar ones. On Earth, this principle dictatesโ that oil and water remain separate. Though, the extreme coldโ and โขunique atmospheric conditions on Titanโ allow for anโ exception.
Researchers replicated Titan’sโฃ surroundings – โฃapproximatelyโฃ minus 183 degrees โCelsius – by combining methane, ethane, and hydrogen cyanide. Spectroscopic analysis revealed that the nonpolar โขmethane โand ethane โmolecules intercalated, โฃor squeezed into, the crystal structure of the polarโข hydrogen cyanide, creatingโ a novel co-crystal.
“This goes against the rule in chemistry,’like dissolves like,’ which basically means โit is indeed unfeasible to combine โthese polar and nonpolar โsubstances,” explained Martin Rahm,leadโ author of the study fromโฃ Chalmers University of Technology,in a statement.
Titan’s atmosphere is rich in nitrogen and simple hydrocarbonโ compounds, including methane and ethane, which cycle through local weather systems โanalogous to Earth’s waterโ cycle.The discovery suggests thatโฃ similar exoticโ solid structures may exist elsewhere โin the Solarโค system and โoffers insights into โtheโ potential for โคcomplex chemistry in environments previously thought inhospitable to such interactions. The team further modeled hundreds โคof potential co-crystal structures to confirm their stability under Titan’s โคconditions.