All the quarter-finals were played without fans, and all confrontations ended with the loss of the hosts in an event that occurred for the first time since 1987.
In the other semi-final, Manchester United will play Chelsea.
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Manchester City dominated the first half, but the only goal came from a penalty kick by de Bruyne after an error against his teammate Gabriel Jesus in the 37th minute.
Newcastle improved after the break and substitute Dwight Gayle missed an easy opportunity to tie.
A minute later, Sterling fired a superb shot from outside the area to ensure City qualified for Arsenal in the semi-finals.
All the quarter-finals were played without fans, and all confrontations ended with the loss of the hosts in an event that occurred for the first time since 1987.
In the other semi-final, Manchester United will play Chelsea.
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